Standard
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AS/NZS ISO 8124.5:2020
[Current]Safety of toys, Part 5: Chemical toys (sets) other than experimental sets
This Standard adopts, ISO 8124 11:2019, which specifies requirements and test methods for the substances and materials used in chemical toys (sets) other than experimental sets.
Published: 11/09/2020
Pages: 67
Table of contents
Cited references
Content history
Table of contents
Header
About this publication
Preface
Foreword
Introduction
1 Scope
2 Normative references
3 Terms and definitions
4 Plaster of Paris (gypsum) moulding sets
4.1 Marking
4.2 First aid information
4.3 Safety rules
5 Oven-hardening plasticised PVC modelling clay sets
5.1 Chemical substances
5.2 Marking
5.3 First aid information
5.4 Safety rules
6 Moulding sets
6.1 Polystyrene granules sets
6.1.1 Chemical substances
6.1.2 Marking
6.1.3 First aid information
6.1.4 Safety rules
6.2 Embedding sets
6.2.1 General
6.2.2 Packaging
6.2.3 Marking
6.2.4 First aid information
6.2.5 Safety rules
7 Adhesives, paints, lacquers, varnishes, thinners and cleaning agents (solvents) supplied or recommended in model sets
7.1 General
7.2 Adhesives
7.2.1 Water-based adhesives
7.2.1.1 General
7.2.1.2 Liquid adhesives for paper and wood
7.2.1.2.1 General
7.2.1.2.2 Packaging
7.2.1.2.3 Marking
7.2.1.2.4 First aid information
7.2.1.3 Adhesive sticks and pastes for paper
7.2.1.3.1 General
7.2.1.3.2 Packaging
7.2.1.3.3 Marking
7.2.1.3.4 First aid information
7.2.2 Solvent-based adhesives
7.2.2.1 General
7.2.2.2 Multi-purpose adhesives
7.2.2.3 Contact adhesives
7.2.2.4 Special adhesives
7.2.2.5 Packaging
7.2.2.6 Marking
7.2.2.7 First aid information
7.2.2.8 Safety rules
7.3 Water-based paints or lacquers
7.3.1 General
7.3.2 Packaging
7.3.3 Marking
7.3.4 First aid information
7.3.5 Safety rules
7.4 Solvent-based paints, lacquers, thinners and cleaning solvents
7.4.1 General
7.4.2 Packaging
7.4.3 Marking
7.4.4 First aid information
7.4.5 Safety rules
8 Marking
8.1 General
8.2 Marking of the primary packaging
8.2.1 General
8.2.2 Manufacturer’s identification
8.2.3 Warning phrases
8.3 Marking of individual containers and any packaging
9 Instructions for use
9.1 General
9.2 Contents list
9.3 Advice for adult supervision
9.4 Safety rules
9.5 Instructions for carrying out the activities
9.6 Spills and disposal of chemicals
10 Test methods
10.1 General
10.2 Determination of plasticisers in oven-hardening polyvinyl chloride (PVC) modelling clay sets
10.2.1 Principle
10.2.2 Standards and reagents
10.2.2.1 Standards
10.2.2.2 Reagents
10.2.3 Apparatus
10.2.3.1
10.2.3.2
10.2.3.3
10.2.3.4
10.2.3.5
10.2.3.6
10.2.3.7
10.2.3.8
10.2.3.9
10.2.3.10
10.2.3.11
10.2.3.12
10.2.3.13
10.2.3.14
10.2.4 Preparation of standard solutions
10.2.4.1 Stock solutions
10.2.4.2 Calibration solutions
10.2.4.3 Stability of standard solutions
10.2.5 Sampling
10.2.6 Sample preparation
10.2.7 Procedure
10.2.7.1 General
10.2.7.2 Extraction of citric acid esters and alkyl sulfonic acid esters
10.2.7.3 Extraction of adipic acid polyesters
10.2.7.4 Evaporation of the solvent and weighing
10.2.7.5 Blank determination
10.2.7.6 GC-MSD determination of citric acid esters and alkyl sulfonic acid esters
10.2.7.7 ATR-FT-IR identification of adipic acid polyesters
10.2.8 Evaluation of results
10.2.8.1 Calculation of solvent-extractable content containing plasticisers
10.2.8.1.1 Mass fraction of hexane extractable material, in %, identified as citric and alkyl sulfonic acid esters by GC-MS
10.2.8.1.2 Mass fraction of methanol extractable material, in %, identified as adipic acid polyester by ATR-FT-IR
10.2.8.1.3 Mass fraction of combined (hexane + methanol) extractable material, in %
10.2.8.2 Calculation and identification of the mass fraction of plasticiser by GC-MS analysis
10.2.8.2.1 Identification of plasticisers
10.2.8.2.2 Calculation of plasticisers content by GC-MS
10.2.8.2.2.1 Mass fraction of citric acid ester, in %, by GC-MS
10.2.8.2.2.2 Mass fraction of alkyl sulfonic acid ester by GC-MS in %
10.2.9 Test report
10.3 Determination of the emission of benzene, toluene and xylenes from oven-hardening plasticised PVC modelling clay sets and polystyrene granules sets
10.3.1 Principle
10.3.2 Standards and reagents
10.3.3 Apparatus
10.3.3.1 Gas chromatograph with mass spectrometer detector (GC-MS)
10.3.3.2 Headspace analysis conditions
10.3.3.3 Other laboratory equipment
10.3.3.3.1
10.3.3.3.2
10.3.3.3.3
10.3.3.3.4
10.3.3.3.5
10.3.3.3.6
10.3.4 Preparation of standard solutions
10.3.5 Sampling
10.3.6 Sample preparation
10.3.7 Procedure
10.3.8 Evaluation of results
10.3.9 Test report
10.3.10 Critical control points
10.4 Determination of styrene content in polystyrene granules
10.4.1 Principle
10.4.2 Standards and reagents
10.4.2.1 Standards
10.4.2.2 Reagents
10.4.3 Apparatus
10.4.3.1
10.4.3.2
10.4.3.3
10.4.3.4
10.4.3.5
10.4.3.6
10.4.3.7
10.4.4 Preparation of standard solutions
10.4.5 Sampling
10.4.6 Sample preparation
10.4.7 Procedure
10.4.8 Evaluation of results
10.4.9 Test report
10.5 Determination of organic solvents
10.5.1 General
10.5.2 Principle
10.5.3 Standards and reagents
10.5.3.1 Standards
10.5.3.2 Reagents
10.5.4 Apparatus
10.5.4.1
10.5.4.2
10.5.4.3
10.5.4.4
10.5.4.5
10.5.4.6
10.5.4.7
10.5.4.8
10.5.4.9
10.5.4.10
10.5.4.11
10.5.4.12
10.5.4.13
10.5.5 Preparation of the standard solutions
10.5.5.1 Stock solutions for the identification and determination of solvents using HS-GC-FID
10.5.5.2 Stock solutions for the identification and determination of solvents using GC-MS
10.5.5.3 Stock solution for the identification and determination of propane-1,2-diol
10.5.5.4 Calibration solutions
10.5.5.4.1 Calibration solutions for the identification of solvents using HS-GC-FID
10.5.5.4.2 Calibration solutions for the identification of solvents in aqueous-based materials
10.5.5.4.3 Calibration solutions for the identification of solvents in solvent-based materials
10.5.5.4.4 Calibration solutions for the determination of solvents using HS-GC-FID
10.5.5.4.5 Calibration solutions for the identification of solvents using GC-MS
10.5.5.4.6 Calibration solution for the determination of solvents using GC-MS
10.5.5.4.7 Calibration solutions for the determination of propane-1,2-diol using GC-FID
10.5.6 Sampling
10.5.7 Sample preparation
10.5.7.1 General
10.5.7.2 Sample preparation for identification and determination of solvents by HS-GC-FID
10.5.7.3 Sample preparation for identification of solvents by GC-MS
10.5.7.3.1 General
10.5.7.3.2 Solvent-based glue, thinner and paint samples
10.5.7.3.3 Aqueous-based glue samples
10.5.7.3.4 Aqueous-based paint samples
10.5.7.4 Sample preparation for determination of certain solvents by GC-MS
10.5.7.5 Sample preparation for determination of propane-1,2-diol using GC-FID
10.5.8 Procedure
10.5.8.1 Identification of solvents using HS-GC-FID
10.5.8.2 Identification of solvents using GC-MS
10.5.8.3 Determination of solvent content by HS-GC-FID
10.5.8.4 Determination of solvent content using GC-MS
10.5.8.5 Determination of propane-1,2-diol by GC-FID
10.5.8.6 Blank determination
10.5.8.6.1 HS-GS-FID blank determination
10.5.8.6.2 GS-MS and GC-FID blank determination
10.5.9 Evaluation of results
10.5.9.1 Calculation of solvent content by HS-GC-FID
10.5.9.2 Calculation of solvent content by GC-MS or GC-FID
10.5.10 Test report
10.6 Combined approach for the determination of plasticisers in solvent-based adhesives and in solvent-based paints or lacquers, film-forming agents in paints and lacquers and modifiers in solvent-based paints or lacquers
10.6.1 Principle
10.6.2 Determination of total extract
10.6.2.1 Standards and reagents
10.6.2.1.1 Standards
10.6.2.1.2 Reagents
10.6.2.2 Apparatus
10.6.2.2.1
10.6.2.2.2
10.6.2.2.3
10.6.2.2.4
10.6.2.2.5
10.6.2.2.6
10.6.2.2.7
10.6.2.2.8
10.6.2.2.9
10.6.2.3 Sampling
10.6.2.4 Sample procedure
10.6.2.5 Procedure
10.6.2.6 Evaluation of results
10.6.3 Identification of nitrocellulose
10.6.3.1 Principle
10.6.3.2 Reagents
10.6.3.3 Apparatus
10.6.3.3.1
10.6.3.3.2
10.6.3.3.3
10.6.3.4 Sampling
10.6.3.5 Sample preparation
10.6.3.6 Procedure
10.6.3.7 Evaluation of results
10.6.4 Determination of plasticisers
10.6.4.1 Principle
10.6.4.2 Standards and reagents
10.6.4.3 Apparatus
10.6.4.4 Preparation of the standard solution
10.6.4.5 Procedure
10.6.4.6 Evaluation of results
10.6.5 Determination of film-forming agents
10.6.5.1 Principle
10.6.5.2 Standards and reagents
10.6.5.2.1 Standards
10.6.5.2.2 Reagents
10.6.5.3 Apparatus
10.6.5.3.1
10.6.5.3.2
10.6.5.3.3
10.6.5.3.4
10.6.5.3.4.1
10.6.5.3.4.2
10.6.5.4 Preparation of standard solutions
10.6.5.4.1 Stock solutions
10.6.5.4.2 Calibration solutions
10.6.5.4.2.1 Calibration solutions for substances 1 to 9 of Table 63
10.6.5.4.2.2 Calibration solutions for substance 10 of Table 63
10.6.5.4.3 Stability of the standard solutions
10.6.5.5 Sampling
10.6.5.6 Procedure
10.6.5.7 Evaluation of results
10.6.6 Determination of the modifiers
10.6.7 Test report
Annex A
Annex B
Annex C
Annex D
D.1 General remark
D.2 Primary packaging (4.1; 5.2; 6.1.2; 6.2.2; 7.2.1.2.2; 7.2.2.6; 7.3.2; 7.4.3; 8.2)
D.3 Minimum age (4.1; 5.2;6.1.2; 6.2.3; 7.2.1.2.3; 7.2.1.3.3; 7.2.2.6; 7.3.3; 7.4.3)
D.4 Benzene (5.1, Table 2; 7.2.2.4, Table 11)
D.5 Preservatives (6.2.1; 7.2.1.1; 7.3.1)
Bibliography
Cited references in this standard
[Current]
Liquid petroleum products - Determination of hydrocarbon types and oxygenates in automotive-motor gasoline and in ethanol (E85) automotive fuel - Multidimensional gas chromatography method
[Current]
Rheology - Part 2: General principles of rotational and oscillatory rheometry
[Current]
Petroleum products - Transparent and opaque liquids - Determination of kinematic viscosity and calculation of dynamic viscosity
Content history
[Current]
[Superseded]
DR AS/NZS ISO 8124.5:2020
AS 8124.5-2003 Rec:2014
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